Shari,
Hope all is well I just got back from a week out of the office and it is real hard to get back into the work mode
Anyway regarding the spray paint I use Rust-Oleum black spray paint.
It seams to work the best for me The tile I did I ran at 100P 30s 500ppi I masked with transfer tape and then spray painted with two or three coats. Then to seal it I sprayed it with clear after all the mask was removed.
Your line width of 0.003 should be O.K. what might be happening is you might not be getting through the top surface of the glaze. These tiles are not very consistent in the glaze coating so it is better to go slower or do two passes in order to be sure you are through the top surface completely.
You could increase your line width to 0.007 to see if it helps it won't be noticeable on the graphic.
Good luck
CEM- Sales and Service of Universal Lasers, Versa Lasers, and Meistergram / H-square engravers.
2800 S. Main St.,Unit C
Santa Ana, Ca 92707
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